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Acid and alkali waste gas spray tower

1. Core FunctionsWaste gas purification: Through counter-current contact between spray liquid (water or special absorbent) and waste gas, harmful pollutants are removed by physical absorption and chemical neutralization to achieve compliant gas discharge. The specific functions are as follows:Absorb...


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Product Introduction

Focus on the production of environmental protection equipment


1. Core Functions

Waste gas purification: Through counter-current contact between spray liquid (water or special absorbent) and waste gas, harmful pollutants are removed by physical absorption and chemical neutralization to achieve compliant gas discharge. The specific functions are as follows:
  1. Absorb acidic and alkaline waste gas (such as HCl, SO₂, NH₃) and reduce corrosivity by neutralization.

  2. Capture particulate matter such as dust and mist droplets to reduce atmospheric dust pollution.

  3. Remove partial organic waste gas (VOCs) and control odor diffusion.

2. Main Applications

It is widely used in industrial and environmental protection fields that generate waste gas. Typical application scenarios are as follows:
  1. Chemical Industry: Treat acidic tail gas, alkaline waste gas and organic volatile substances generated by chemical reactions.

  2. Electroplating Industry: Purify acid mist (chromic acid mist, hydrochloric acid mist) volatilized from electroplating tanks to protect operators.

  3. Coating Industry: Absorb paint mist and VOCs generated during spraying to reduce peculiar odor.

  4. Metallurgical Industry: Treat sulfur-containing waste gas and dust from smelting to reduce air pollution.

  5. Electronic Industry: Purify acidic waste gas produced by semiconductor manufacturing and circuit board etching.

  6. Pharmaceutical Industry: Treat organic waste gas and corrosive gas generated in drug synthesis.

  7. Sewage Treatment Plant: Remove odorous gas such as hydrogen sulfide and ammonia from aeration tanks and sludge treatment areas.

  8. Boiler Flue Gas Treatment: Complete desulfurization and dust removal pretreatment to ensure flue gas compliance.

喷淋塔的作业与用途

Application Scope of Spray Tower

Spray towers are mainly used for waste gas purification, covering various industries and pollutant types. The detailed scope is as follows:

1. Applicable Pollutant Types

  1. Acid and Alkaline Gas: Hydrochloric acid mist, sulfuric acid mist, nitrogen oxides, ammonia and alkaline tail gas.

  2. Particulate Matter: Industrial dust, paint mist, liquid droplets and smoke.

  3. Organic Waste Gas: Partial VOCs and odorous gas (hydrogen sulfide, methyl mercaptan).

  4. Other Functions: High-temperature flue gas cooling pretreatment and gas humidification.

2. Applicable Industries

  1. Chemical & Petrochemical Industry: Treat acid-base tail gas and organic volatile substances.

  2. Electroplating & Surface Treatment Industry: Purify corrosive gas such as acid mist and chromium mist.

  3. Spraying & Coating Industry: Capture paint mist and remove spraying VOCs and odor.

  4. Metallurgy & Steel Industry: Complete desulfurization and dust removal for smelting flue gas.

  5. Electronic & Semiconductor Industry: Treat acidic waste gas from etching and cleaning processes.

  6. Pharmaceutical & Pesticide Industry: Purify organic and corrosive gas from synthetic reactions.

  7. Environmental Protection Field: Odor treatment for sewage plants and garbage transfer stations.

  8. Energy & Boiler Industry: Flue gas desulfurization, cooling and dust removal.

  9. Printing & Packaging Industry: Remove VOCs and odor volatilized by ink.

  10. Food Processing Industry: Eliminate oil fume and peculiar smell during production.

Classification of Spray Tower Treatment Processes

Based on the gas-liquid mass transfer principle, spray towers are classified by treatment objects, chemical types and reaction mechanisms. The main processes are listed as follows:

1. Classification by Treatment Principle

1.1 Acid and Alkaline Waste Gas Spray Tower

1.2 Physical Absorption Process

Water or organic solvent is used as spray liquid. Relying on the solubility of pollutants in liquid, particulate matter (dust, paint mist) and water-soluble VOCs in waste gas are physically captured without chemical reaction.

1.3 Oxidation-Reduction Process

For waste gas containing reductive or oxidative pollutants, oxidants (such as NaClO solution) or reducing agents are added. Toxic and harmful pollutants are converted into harmless substances through oxidation-reduction reaction (e.g., sulfide is oxidized into sulfate).

1.4 Combined Adsorption-Absorption Process

Adsorbents such as activated carbon and molecular sieve are added into the spray liquid. It combines liquid absorption and solid adsorption to enhance the removal efficiency of VOCs and odorous gas (hydrogen sulfide, methyl mercaptan).

2. Classification by Gas-Liquid Contact Mode

2.1 Counter-current Spray Process

Waste gas rises from the tower bottom while spray liquid flows downward from the tower top. The reverse flow ensures sufficient gas-liquid contact and high purification efficiency. It is the most widely used process.

2.2 Co-current Spray Process

Waste gas and spray liquid flow downward from the tower top together. It is suitable for high-concentration and large-flow waste gas with low pressure loss, while its purification efficiency is slightly lower than the counter-current process.

2.3 Cross-flow Spray Process

Waste gas flows horizontally and spray liquid sprays vertically to form cross contact. It is applicable to limited installation space with a compact structure.

3. Classification by Special Functions

3.1 Desulfurization Spray Process

Aiming at boiler and metallurgical flue gas, limestone-gypsum method and ammonia method are adopted. The spray liquid absorbs SO₂ to achieve compliant flue gas desulfurization.

3.2 Paint Mist Capture Process

Specially used in spraying industry. Paint mist coagulant is added into the spray liquid to condense and settle paint mist particles, preventing equipment blockage and recycling partial paint materials.

3.3 Deodorization Spray Process

Used for odorous gas in sewage plants and garbage stations. Deodorants (biological or chemical deodorant) are added to decompose and absorb odorous components.

3.4 Cooling Pretreatment Process

Applied to high-temperature flue gas (such as boiler flue gas). Cold water spraying cools down the gas to avoid high-temperature damage to subsequent equipment, and removes dust preliminarily.

Detailed Structure of Spray Tower Demister

The core function of a demister is to separate entrained mist droplets and fine liquid droplets from waste gas. It prevents liquid carrying in fans, pipeline corrosion and liquid discharge of tail gas. The structure is designed for high-efficiency collection and low-resistance emission, consisting of the following components:

1. Core Structural Components

1.1 Demisting Element (Core Collection Part)

As the key component determining demisting efficiency, common types and structural characteristics are as follows:
  • Baffle Type: Assembled by multiple wave-shaped or folded plates with diversion grooves at a specific angle. When waste gas passes through the channel, mist droplets collide with the plate wall due to inertia, attach to the surface and flow down. It has simple structure and low resistance, suitable for medium and low-concentration mist.

  • Wire Mesh Type: Woven by multi-layer metal or plastic wires to form a porous mesh structure. Fine mist droplets are intercepted by mesh fibers and condensed into large droplets. It owns high collection efficiency for tiny droplets but is easy to block and requires regular cleaning.

  • Honeycomb Type: Composed of hexagonal honeycomb channels with smooth inner walls. Mist droplets collide and settle on the wall. It features compact structure and high compression resistance, suitable for high-flow working conditions.

1.2 Support Structure

It fixes demisting elements to ensure stable operation under airflow impact:
  • Support Beam: Arranged horizontally or longitudinally, generally made of anti-corrosion carbon steel, stainless steel or FRP with sufficient structural strength.

  • Fixing Bracket: Connected with the tower body to firmly fix demisting elements and avoid displacement and deformation.

1.3 Liquid Collection and Discharge System

  • Liquid Collection Tank: Installed under demisting elements to receive falling droplets with a slope for liquid convergence.

  • Liquid Guide/Return Pipe: Transports collected liquid back to the circulating water tank for recycling and waste reduction.

1.4 Flushing System (Optional for Blockage-prone Conditions)

  • Flushing Pipe: Arranged above demisting elements and equipped with spray nozzles.

  • Flushing Pump and Valve: Regularly spray clean water to remove scale and sediment on the demister and prevent blockage.

1.5 Tower Connection Structure

The demister is integrally connected with the spray tower through flanges and bolts. Sealing gaskets are installed at joints to ensure air tightness and prevent gas leakage.

2. Key Structural Design Parameters

  1. Channel Flow Velocity: A reasonable flow velocity is required. Low velocity leads to low collection efficiency, while excessive velocity causes secondary entrainment of droplets.

  2. Baffle Angle / Mesh Layers: The baffle angle is generally 30°-60°. More mesh layers bring higher efficiency but greater airflow resistance.

  3. Liquid Discharge Slope: The slope of the liquid collection tank is usually 3°-5° to ensure rapid liquid discharge and avoid liquid accumulation.

  4. Material Selection: FRP and PP are commonly used for acidic waste gas; stainless steel is applied for high-temperature working conditions.

3. Typical Installation Position

The demister is generally installed at the top of the spray tower and above the spraying area. As the last treatment link before gas discharge, it guarantees qualified emission of purified waste gas.

Types, Functions and Replacement Cycle of Spray Tower Packing

As the core gas-liquid mass transfer component, tower packing is classified by material and structure as follows:

酸碱废气喷淋塔

1. Types and Characteristics of Packing

1.1 Classification by Material

  • Plastic Packing: Made of PP, PE, PVC, etc. It features acid and alkali resistance, light weight and low cost. Suitable for medium and low temperature (≤80℃) acid-base waste gas. Common types include pall ring, raschig ring and cascade ring.

  • Ceramic Packing: Resistant to high temperature (≤1000℃) and strong corrosion with smooth liquid-adhering surface. Suitable for high-temperature and strongly corrosive waste gas. It is brittle and heavy, requiring careful transportation and installation. Typical products include ceramic pall ring and saddle ring.

  • Metal Packing: Made of stainless steel or anti-corrosion carbon steel. It has high strength, high temperature resistance and large flux, suitable for high-pressure and high-temperature working conditions such as flue gas desulfurization. It has poor corrosion resistance and high cost. Common types are metal pall ring and wire mesh corrugated packing.

1.2 Classification by Structure

  • Random Packing: Stacked independently in single particles, such as pall ring, raschig ring and cascade ring. It is easy to assemble and disassemble, applicable to small and medium-sized spray towers.

  • Structured Packing: Arranged in regular shapes such as corrugated packing and honeycomb packing. It realizes uniform gas-liquid distribution and high mass transfer efficiency for large-scale high-efficiency treatment, while it is difficult to clean after blockage.

2. Core Functions of Packing

  1. Expand Contact Area: The porous and special geometric structure greatly increases the contact area between spray liquid (liquid phase) and waste gas (gas phase) for mass transfer reaction.

  2. Prolong Contact Time: Disturb the gas and liquid flow path, slow down the flow speed and extend the reaction time to improve pollutant removal efficiency.

  3. Uniform Gas-Liquid Distribution: Avoid channel flow and wall flow to ensure consistent treatment effect in all areas of the tower.

  4. Strengthen Mass Transfer Efficiency: Optimize gas-liquid contact state, accelerate pollutant transfer from gas phase to liquid phase, improve reaction rate and reduce outlet waste gas concentration.

3. Replacement Cycle and Judgment Standard

3.1 Conventional Replacement Cycle

  • Random Plastic Packing: 1-3 years, depending on corrosion degree and blockage condition.

  • Ceramic Packing: 3-5 years with high temperature and corrosion resistance; avoid breakage during operation.

  • Metal Packing: 2-4 years; shortened to 1-2 years for corrosive waste gas.

  • Structured Packing: 2-3 years; shortened to 6-12 months for waste gas with high dust concentration due to easy blockage.

3.2 Replacement Judgment Criteria

  • Decreased Treatment Efficiency: The outlet waste gas concentration exceeds the standard continuously, which cannot be improved even after adjusting spray liquid concentration and flow.

  • Increased Pressure Loss: The internal tower pressure difference exceeds 1.5 times the design value, causing obvious fan overload.

  • Abnormal Packing Condition: Severe scaling, blockage, collapse and breakage, or uncleanable surface pollutants.

  • Poor Spraying Effect: Uneven liquid distribution caused by packing blockage leads to local dry areas inside the tower.

3.3 Influencing Factors of Service Life

  • Waste Gas Property: High-concentration, high-humidity and viscous pollutants accelerate packing blockage and corrosion.

  • Spray Liquid Quality: Excessive reagent concentration and impurities cause packing scaling.

  • Maintenance Frequency: Regular cleaning and backflushing prolong service life; otherwise, the service life will be shortened.

Difference Between Positive Pressure and Negative Pressure Spray Tower

The core difference lies in the internal pressure state, which directly affects gas flow power, sealing requirements and application scenarios. Essentially, it is the difference between active air supply and passive air intake.

1. Core Difference: Pressure State and Gas Flow Logic

1.1 Positive Pressure Spray Tower

Pressure State: Internal pressure is higher than atmospheric pressure (0.01-0.05MPa normally).
Gas Flow: The front-end blower presses waste gas into the tower, and the gas passes through the packing layer to contact with absorbent under positive pressure.
Power Source: The front-end air supply fan provides power to overcome internal tower resistance.

1.2 Negative Pressure Spray Tower

Pressure State: Internal pressure is lower than atmospheric pressure (-0.01~-0.03MPa normally).
Gas Flow: The rear-end induced draft fan extracts internal gas to form negative pressure, which sucks waste gas into the tower for purification.
Power Source: The rear-end induced draft fan forms a negative pressure environment, and waste gas flows in naturally under pressure difference.

2. Comparison of Key Characteristics

Comparison Dimension
Positive Pressure Spray Tower
Negative Pressure Spray Tower
Sealing Requirement
Low (basic sealing is enough)
High (strict sealing to prevent air infiltration)
Gas Leakage Risk
Low (leakage outward and easy to detect)
Low to Medium (air infiltration reduces purification efficiency)
Fan Position
Front end (air supply side)
Rear end (exhaust side)
Fan Corrosion Risk
High (contact with untreated waste gas)
Low (contact with purified clean gas)
Applicable Waste Gas
Low-concentration, non-corrosive, non-flammable gas
High-concentration, corrosive, flammable and odorous gas
Operation Stability
Affected by air pressure with fluctuating air volume
Stable negative pressure with flexible air volume adjustment

3. Application Selection Suggestions

3.1 Selection for Positive Pressure Tower

Suitable for low-concentration and non-corrosive waste gas (such as workshop dust and slight odor). It features low cost and simple installation, applicable to sites without explosion-proof requirements.

3.2 Selection for Negative Pressure Tower

Suitable for harsh waste gas with strong corrosivity (acid-base mist), high toxicity (hydrogen cyanide), flammability (benzene series) and strong odor. It ensures no gas leakage and prolongs fan service life with high stability requirements.

4. Supplementary Notes

  • For positive pressure towers, the front-end fan requires anti-corrosion protection. Anti-corrosion fans or pretreatment devices shall be equipped for corrosive waste gas.

  • Sealing performance is critical for negative pressure towers. Reinforce the tightness of tower body, pipelines and flanges to avoid efficiency reduction caused by air leakage.

  • Both towers share the same purification principle (gas-liquid contact and pollutant absorption), differing only in power and pressure design for flexible selection according to waste gas characteristics.

Respective Application Scenarios of Positive and Negative Pressure Spray Towers

1. Conclusion

Positive pressure spray tower: Applicable to ordinary waste gas with low concentration, no strong corrosion and no flammable risk.
Negative pressure spray tower: Applicable to harsh waste gas with high concentration, strong corrosion, high toxicity, flammability and strong odor.

2. Application Scenarios of Positive Pressure Spray Tower

2.1 Waste Gas Characteristics

Low concentration (dust ≤50mg/m³, VOCs ≤100mg/m³), non-corrosive, non-flammable and low-toxicity.

2.2 Typical Industries & Processes

  • Purification of dust and cutting oil mist in mechanical processing workshops;

  • Slight odor treatment in food processing and packaging industries;

  • Purification of non-corrosive dust (plastic dust, welding smoke) in electronic factories;

  • Low-concentration paint mist pretreatment for small coating workshops.

2.3 On-site Requirements

No strict sealing and explosion-proof requirements, low equipment cost, simple installation and good ventilation conditions.

3. Application Scenarios of Negative Pressure Spray Tower

3.1 Waste Gas Characteristics

High concentration, strong corrosivity (acid-base mist, salt mist), high toxicity (hydrogen cyanide, chlorine), flammability (benzene series, alkane) and strong odor.

3.2 Typical Industries & Processes

  • Treatment of acid mist and cyanide-containing waste gas in chemical and electroplating industries;

  • Purification of coke oven flue gas and sulfur-containing/nitrogen-containing waste gas in coking and metallurgical industries;

  • Treatment of high-concentration VOCs and toxic gas in pharmaceutical and chemical synthesis industries;

  • Treatment of high-concentration paint mist and solvent waste gas (toluene, xylene) in coating and printing industries;

  • Odor purification (hydrogen sulfide, ammonia) in garbage disposal and sewage treatment plants.

3.3 On-site Requirements

High requirements for environmental compliance and safety protection. It is necessary to avoid gas leakage and extend the service life of fans without contacting untreated waste gas.